Humetin, Tobrand DM-01, DBDCB, Bromonitrile
Alias: 2-Bromo-2-(bromomethyl)pentanedinitrile; 2-Bromo-(2-bromomethyl)glutaronitrile; DBDCB
Chemical name
1, 2-dibromo-2,4-dicyanobutane, 1, 2-dibromo-2,4-dicyanobutane
Toxicity
Brominonitrile is a low-toxicity fungicide according to the toxicity classification standard of pesticide in China. The acute transoral LD50 of male rats was 637mg/kg, and that of female rats was 414mg/kg. DBDCB was diluted to 0.3% without any irritation to the skin and mucous membranes of rabbits. There is no teratogenic, mutagenic or carcinogenic effect on animals in the test dose.
Physicochemical properties
Slightly irritating smell. Melting point 52.5-53.2°C, density 970g/ml (20°C), vapor pressure 6.70*10Pa-3 (25°C), insoluble in water (0.212g/100ml 20°C), soluble in acetone, benzene, chloroform, ethanol and other organic solvents.
use
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It is a broad spectrum, high efficiency and low toxicity fungicide, which can inhibit and eradicate the growth of fungi, bacteria and algae, and has a better control effect on crop diseases, and has special effect on anthrax. Widely used in fruit trees, grapes, vegetables, cotton, peanuts, watermelon, tobacco, tea tree, flowers and other crops, control anthracnose, black star disease, scab disease, powdery mildew, rust, standing blight, quench disease, root and stem rot, canker disease, bacterial wilt, keratosis and other fungal, bacterial diseases. The method of application is flexible, and foliar spray, seed treatment and soil irrigation all show good control effect. It is also suitable for eliminating algae in lake environmental treatment and improving the water quality of fishing ponds. Textiles, leather and other anti-corrosion, anti-gas, etc. [1]
appearance
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White or light yellow crystal powder. Effective content :≥ 95%,≥ 98%
Production method
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Brominonitrile was prepared from acrylonitrile by 2-methylene glutardinitrile, which was then added with bromine. In the presence of a catalyst, acrylonitrile dimerized to form 2-methylene-glutaronitrile at 25-30 ºC, and then 213g 97% of 2-methylene-glutaronitrile was passed into bromine 228g at 100ºC until the reaction liquid was light yellow, which was the reaction endpoint. Then a dispersant was added to the reaction solution, and a certain amount of solvent was added, stirring while adding, granular crystals were precipitated, stratified, the solvent layer was removed, pumped and dried to obtain solid brominonitrile. [2]
package
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The standard package is 20KG and 25KG net weight, lined with double plastic bags, full cardboard bucket packaging, can also be packed according to customer requirements.
storage
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Sealed, moisture-proof, shelf life of 5 years